... and secondary alcohols under mild conditions to give N-(alpha-alkoxyalkyl) amides 3 in good yield. ... 1,2 Various heteroatom-based stabilizing groups, located at an ortho-position, have been used ... with the methoxide as its leaving group.
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In chemistry, a leaving group is a molecular fragment that departs with a pair of electrons in heterolytic bond cleavage. Leaving groups can be anions, cations or neutral molecules...
en.wikipedia.orgThe catalysts showed good activity at two investigated sspH values of 8.8 and 11 (in methanol). Despite the fact that the methoxide promoted reactions for the ...
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(Germany). GRP (Good ... The effect of adding potassium methoxide to the reaction mixture after ... [18F]fluoride with the leaving group of the substrate molecule.
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The catalysis afforded by the metal ions is remarkable, being about 10(6)-fold and 10(8)-fold for poor and good leaving groups, respectively, relative to the ...
www.researchgate.net2 key ways to make alcohols into good leaving groups; add acid or convert to tosylates/mesylates. Application to SN1 and SN2 examples.
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Request PDF | ChemInform Abstract: Direct Synthesis of Alkynylstannanes: ZnBr 2 Catalyst for the Reaction of Tributyltin Methoxide and Terminal Alkynes.
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