... and secondary alcohols under mild conditions to give N-(alpha-alkoxyalkyl) amides 3 in good yield. ... 1,2 Various heteroatom-based stabilizing groups, located at an ortho-position, have been used ... with the methoxide as its leaving group.

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In chemistry, a leaving group is a molecular fragment that departs with a pair of electrons in heterolytic bond cleavage. Leaving groups can be anions, cations or neutral molecules...

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The catalysts showed good activity at two investigated sspH values of 8.8 and 11 (in methanol). Despite the fact that the methoxide promoted reactions for the ...

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(Germany). GRP (Good ... The effect of adding potassium methoxide to the reaction mixture after ... [18F]fluoride with the leaving group of the substrate molecule.

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The catalysis afforded by the metal ions is remarkable, being about 10(6)-fold and 10(8)-fold for poor and good leaving groups, respectively, relative to the ...

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2 key ways to make alcohols into good leaving groups; add acid or convert to tosylates/mesylates. Application to SN1 and SN2 examples.

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Request PDF | ChemInform Abstract: Direct Synthesis of Alkynylstannanes: ZnBr 2 Catalyst for the Reaction of Tributyltin Methoxide and Terminal Alkynes.

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