Potassium methoxide is the alkoxide of methanol with the counterion potassium and is used as a strong base and as a catalyst for transesterification...
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... (degenerate racemization) and tautomerization of methoxide ion tautomer. // Can. ... Kern J.M., Federlin P. Correlation Eox de carbanions/pKa de leurs acides ...
www.dissercat.com... by methoxide and 4,5-dimethoxy-2-methylbenzaldehyde was obtained from 12 in 87% yield by a pyridine-catalyzed Vilsmeier reaction using DMF-POCl3. Ad.
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Methoxides are organic salts and the simplest alkoxides. Sodium methoxide and potassium methoxide have widespread use, though other metal-cation variants such as lithium methoxide, rubidium methoxide, and caesium methoxide exist as well.
en.wikipedia.org... значения pKa молекул метанола, ацетилена и фенилацетилена хорошо ... and phenylacetylene with the methoxide ion in DMSO solution we can expect ...
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... Patrick C. R. Kinetics of nucleophilic substitution in polyfluoroaromatics compounds. The rek* • action of sodium methoxide with hexafluorobenzene. -J« Chem ...
fizmathim.com(II) K - Na suspensions, and (III) various compositions of Al-I-methoxide and diffe- rent electron accepting compounds, the latter having stereoelective properties.
polymsci.ruIn this case, a “spectrum” of pKa values appears because of influence of ionized ... (Polyfluoro)-nitrobenzenes were reacted with 2 equiv of sodium methoxide ...
www.researchgate.net... ab initio calculation of the pKa using a new parametrization of the polarizable ... Miller S.I. Vinylation: Kinetics and Mechanism of the Methoxide-catalyzed ...
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4 igk»3°+= (0.26*0.01)pKa + (I.16*0.04) ... pect to pKa values of diphenylgUanidine in nitromethane have been ... dium methoxide (see Eqs. (1) - (4)). The rate of ...
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constant of the functional groups (pKa = 6,59), and the values of the ion ... was perfomed by the Zempman method using sodium methoxide in methanol [4].
conf-prfn.orgDespite the fact that the methoxide promoted reactions for the four substrates span a range of 20 000-fold, the apparent second order rate constants (k2app) for ...
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